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List of Anode and Cathode Battery Materials

Introduction to Anode and Cathode Battery Materials

Batteries power modern life, from electric vehicles to cell phones, and their operation is based essentially on the materials utilized for their anode and cathode. The anode and cathode electrodes exchange energy between them through electrochemical reactions to store and supply energy.

The anode is the negative electrode where oxidation occurs when releasing energy, emitting electrons to power devices. Conversely, the cathode is the positive electrode where reduction takes place, accepting those electrons in order to close the loop. Between them, there is an electrolyte that facilitates passage of ions without direct electron transfer, facilitating energy exchange in a useful way. 

Let’s learn about the list of anode and cathode battery materials.

Anode Materials: The Pillar of Energy Storage

  • The most common anode material employed in lithium-ion batteries is graphite, valued for its stability, low cost, and long cycle life.
  • But its low energy has stimulated research for alternatives like silicon, which has much higher theoretical energy but is beset with severe expansion during charging. To get around this, researchers are developing silicon-graphite composites that integrate performance and durability.
  • Lithium metal anodes are also a promising direction, the highest energy density of any but mandating that the issues of dendrite formation need to be broken, possibly with solid-state battery designs.
  • Other emerging players include lithium titanate for fast charging and sodium-based anodes for more sustainable battery chemistries.

Cathode Materials: Setting Voltage and Stability

Cathode materials have an equally significant role to play in defining a battery's properties.

  • Lithium cobalt oxide remains widely used in consumer electronics due to its energy density, but its cost and heat constraints have generated interest in alternatives.
  • Lithium iron phosphate has been popularized for use in electric vehicles and grid batteries due to its safety, long lifespan, and lower price despite its lower energy density.
  • Nickel cathodes, such as NMC and NCA chemistries, are a compromise between energy and power, with high-nickel compositions becoming increasingly widespread for electric vehicle use where more range is needed.
  • Lithium manganese oxide offers enhanced thermal resistance for medical devices and power equipment, with future breakthroughs in the form of sulfur cathodes and sodium-ion materials to further enhance performance and sustainability.

The Future of Battery Electrodes  

Battery technology will continue rapidly improving in the future. 

  • Silicon-dense anodes could double energy density, while cobalt-free cathodes could reduce cost and ethics concerns.
  • Solid-state batteries, with the potential for improved safety and performance, represent another gigantic frontier.

Summary Table: List of Anode and Cathode Battery Materials

Material

Chemical Formula

Voltage (V vs Li/Li+)

Capacity (mAh/g)

Energy Density (Wh/kg)

Cycle Life

Key Applications

Advantages

Disadvantages

Anode Materials

Graphite

C

0.05-0.2

372

~350

500-1000

Smartphones, EVs, laptops

Low cost, stable, long cycle life

Limited capacity

Silicon

Si

0.4

4200 (theoretical)

~800 (composite)

100-300

Next-gen EVs (Tesla 4680)

Ultra-high capacity

300% volume expansion

Lithium Titanate (LTO)

LiTiO₁₂

1.55

175

~80

3000-5000

Fast-charging EVs, grid storage

Excellent cycle life, safety

Low energy density

Lithium Metal

Li

0

3860

~1000

50-100

Solid-state batteries (experimental)

Highest energy density

Dendrite formation

Cathode Materials

Lithium Cobalt Oxide (LCO)

LiCoO

3.7

140-160

200-250

500-800

Smartphones, laptops

High energy density

Expensive, thermal runaway risk

Lithium Iron Phosphate (LFP)

LiFePO

3.2

160-170

150-200

2000-3000

EVs (Tesla Model 3), grid storage

Safe, low cost, long lifespan

Lower energy density

NMC (Nickel Manganese Cobalt)

LiNiMnCoO

3.6-3.8

180-220

250-300

1000-2000

EVs (Chevy Bolt), power tools

Balanced energy/power

Cobalt dependency

NCA (Nickel Cobalt Aluminum)

LiNiCoAlO

3.6-3.8

180-220

250-300

800-1500

EVs (Tesla Model S/X)

High energy density

Thermal instability

Lithium Manganese Oxide (LMO)

LiMnO

3.7-4.0

100-120

150-200

500-1000

Power tools, medical devices

Fast charging, thermal stability

Lower capacity

Emerging Materials

Silicon-Graphite Composite

Si/C

0.1-0.4

450-600

400-500

300-500

Next-gen EVs

Improved capacity vs. graphite

Moderate expansion issues

Sulfur Cathode

S

2.1

1675

~500 (theoretical)

50-100

Experimental Li-S batteries

Ultra-high capacity

Polysulfide shuttle effect

Sodium-Ion Cathode (P2-type)

Naₓ[NiMnCo]O

3.0-3.3

120-160

150-200

500-1000

Low-cost energy storage

Cobalt-free, sustainable

Lower energy vs. lithium

For more information, please check Stanford Electronics.

Conclusion

As the technologies continue to evolve, they will provide more powerful, more durable, and cleaner energy storage technologies for a more electrified world. Ongoing breakthroughs in cathode and anode materials remain at the center of what will make the next generation of battery technology possible.

 

 

Reference:

[1] Gao, Dexin & Liu, Xin & Zhu, Zhenyu & Yang, Qing. (2023). A hybrid CNN-BiLSTM approach for remaining useful life prediction of EVs lithium-Ion battery. Measurement and Control. 56. 002029402211036. 10.1177/00202940221103622.

 

About The Author

James Carter

James Carter is a skilled professional writer at Stanford Electronics, specializing in creating clear, engaging, and informative content about semiconductor materials and advanced technologies. With a focus on delivering precision and simplicity, James ensures complex topics are accessible to a broad audience.

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